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Macromolecular & Polymer Chemistry: Foundational Epochs & Key Milestones

Encyclopedia/1. The Cosmos & The Natural World/2. Physics & Chemistry/03. Chemistry & Periodic Table of Elements  •  Curated by Admin Timeline.sg

Historical events timeline.

Chronological Storyline (42 Milestones)

4500 BCE

Natural Latex Use in Mesoamerica

Olmec and later Mesoamerican peoples use natural latex from rubber trees to make balls, figurines, and waterproofing. #polymer #history

Natural Latex Use in Mesoamerica
Natural Latex Use in Mesoamerica
By Gradstudentscholar - Own work, CC BY-SA 4.0, https://commons.wikimedia.org/w/index.php?curid=89532135
1600 BCE

Natural Polymers in Ancient China

Chinese artisans use lacquer (urushiol) from tree sap as a natural polymer coating for wood and other materials. #polymer #history

Natural Polymers in Ancient China
Natural Polymers in Ancient China
By Unknown author - This file was donated to Wikimedia Commons as part of a project by the Metropolitan Museum of Art. See the Image and Data Resources Open Access Policy, CC0, https://commons.wikimedia.org/w/index.php?curid=58752728
1500 BCE

Protein-Based Polymers Used in Egypt

Ancient Egyptians use collagen-based animal glues for woodworking and attaching pigments. #polymer #history

Protein-Based Polymers Used in Egypt
Protein-Based Polymers Used in Egypt
By Simon Eugster – Simon / ?! 12:57, 8 May 2008 (UTC) - Own work, CC BY-SA 3.0, https://commons.wikimedia.org/w/index.php?curid=4012429
65 CE

Pliny the Elder Describes Rubber

Roman author Pliny the Elder describes rubber obtained from the 'Ficus elastica' tree, noting its elasticity and water resistance. #polymer #history

Pliny the Elder Describes Rubber
Pliny the Elder Describes Rubber
By Geoffrey - Cesare Cantù, Grande Illustrazione del Lombardo Veneto ossia storia delle città, dei borghi etc., Milano 1859, Vol. III, Public domain, https://commons.wikimedia.org/w/index.php?curid=9466113
1492 CE

Columbus Encounters Natural Rubber

Christopher Columbus observes indigenous people in Haiti playing with rubber balls, introducing natural rubber to Europe. #polymer #history

1839 CE

Charles Goodyear Discovers Vulcanization

Charles Goodyear accidentally discovers that heating natural rubber with sulfur creates a durable, elastic material (vulcanized rubber), enabling widespread commercial use. #polymer #chemistry

Charles Goodyear Discovers Vulcanization
Charles Goodyear Discovers Vulcanization
By Southworth & Hawes - http://images.zeno.org/Fotografien/I/big/PHO03916.jpg, Public domain, https://commons.wikimedia.org/w/index.php?curid=93310352
1846 CE

Christian Schönbein Invents Nitrocellulose

Christian Friedrich Schönbein treats cellulose with nitric acid to produce nitrocellulose, an early semi-synthetic polymer used in explosives and later as a plastic. #polymer #chemistry

Christian Schönbein Invents Nitrocellulose
Christian Schönbein Invents Nitrocellulose
By Unknown author, Public domain, https://commons.wikimedia.org/w/index.php?curid=955075
1862 CE

Alexander Parkes Introduces Parkesine

Alexander Parkes displays Parkesine, made from nitrocellulose and camphor, at the Great International Exhibition in London. It is considered the first man-made plastic. #polymer #history

1869 CE

John Wesley Hyatt Invents Celluloid

John Wesley Hyatt develops celluloid, a thermoplastic material from nitrocellulose and camphor, used for billiard balls, film, and dental plates. #polymer #chemistry

1884 CE

Hilaire de Chardonnet Invents Rayon

Hilaire de Chardonnet patents artificial silk (rayon) made from nitrocellulose, the first commercial synthetic fiber. #polymer #textiles

Hilaire de Chardonnet Invents Rayon
Hilaire de Chardonnet Invents Rayon
By Maxim Bilovitskiy - Own work, CC BY-SA 4.0, https://commons.wikimedia.org/w/index.php?curid=44965866
1907 CE

Leo Baekeland Creates Bakelite

Leo Baekeland synthesizes Bakelite, the first fully synthetic thermosetting plastic made from phenol and formaldehyde, marking the birth of the modern plastics industry. #polymer #chemistry

Leo Baekeland Creates Bakelite
Leo Baekeland Creates Bakelite
By Original: MarkusZi Vector: Dirk Hünniger - Bakelit Struktur.png, CC BY-SA 3.0, https://commons.wikimedia.org/w/index.php?curid=20188781
1910 CE

Hermann Staudinger Proposes Macromolecular Hypothesis

Hermann Staudinger proposes that polymers are long chains of repeating units held together by covalent bonds, challenging the prevailing colloidal theory. #polymer #science

Hermann Staudinger Proposes Macromolecular Hypothesis
Hermann Staudinger Proposes Macromolecular Hypothesis
By Nobel Foundation - Les Prix Nobel en 1953, Public domain, https://commons.wikimedia.org/w/index.php?curid=18542861
1920 CE

Staudinger Publishes Paper on Polymerization

Hermann Staudinger publishes a seminal paper 'Über Polymerisation' outlining the macromolecular theory, laying the foundation for polymer chemistry. #polymer #chemistry

1926 CE

Staudinger Confirms Macromolecular Theory

Hermann Staudinger provides experimental evidence for macromolecules through viscosity and filtration studies, leading to widespread acceptance. #polymer #science

1928 CE

Wallace Carothers Joins DuPont

Wallace Carothers begins working at DuPont, where he leads research that leads to the invention of neoprene and nylon. #polymer #chemistry

Wallace Carothers Joins DuPont
Wallace Carothers Joins DuPont
By Unknown photographer - http://listverse.com/2007/10/07/top-10-scientists-who-committed-suicide/, Public domain, https://commons.wikimedia.org/w/index.php?curid=13295767
1931 CE

Discovery of Neoprene

Wallace Carothers and his team synthesize neoprene (polychloroprene), the first successful synthetic rubber, used for oil-resistant applications. #polymer #chemistry

Discovery of Neoprene
Discovery of Neoprene
By Mark.murphy - English Wikipedia, Public domain, https://commons.wikimedia.org/w/index.php?curid=866990
1935 CE

Invention of Nylon

Wallace Carothers invents nylon, the first synthetic fiber made from polyamide, revolutionizing textiles and industry. #polymer #textiles

Invention of Nylon
Invention of Nylon
By User:Innerstream - Own work, Public domain, https://commons.wikimedia.org/w/index.php?curid=112727156
1942 CE

Polyethylene Production Begins

Low-density polyethylene (LDPE) is first produced by Imperial Chemical Industries (ICI) using high-pressure processes, becoming a major packaging material. #polymer #chemistry

Polyethylene Production Begins
Polyethylene Production Begins
By Lluis tgn - Own work, CC BY-SA 3.0, https://commons.wikimedia.org/w/index.php?curid=12749082
1953 CE

Karl Ziegler Discovers Ziegler-Natta Catalysts

Karl Ziegler discovers catalysts that enable the synthesis of high-density polyethylene (HDPE) and other polyolefins at low pressure, revolutionizing polymer production. #polymer #chemistry

Karl Ziegler Discovers Ziegler-Natta Catalysts
Karl Ziegler Discovers Ziegler-Natta Catalysts
By Unknown author - http://www.nobelprize.org/nobel_prizes/chemistry/laureates/1963/, Public domain, https://commons.wikimedia.org/w/index.php?curid=18334634
1954 CE

Giulio Natta Improves Ziegler Catalysts

Giulio Natta expands Ziegler's work to produce isotactic polypropylene, a highly crystalline and useful polymer. #polymer #chemistry

Giulio Natta Improves Ziegler Catalysts
Giulio Natta Improves Ziegler Catalysts
By Unknown (Mondadori Publishers) - http://www.gettyimages.co.uk/detail/news-photo/portrait-of-italian-engineer-giulio-natta-1960s-news-photo/174304752, Public domain, https://commons.wikimedia.org/w/index.php?curid=41259480
1956 CE

Paul Flory Develops Flory-Huggins Theory

Paul Flory establishes the thermodynamic theory of polymer solutions (Flory-Huggins theory), providing a theoretical framework for polymer physics. #polymer #science

Paul Flory Develops Flory-Huggins Theory
Paul Flory Develops Flory-Huggins Theory
By Unknown (Associated Press) - [1], Public domain, https://commons.wikimedia.org/w/index.php?curid=70925529
1960 CE

Polycarbonate Introduced by GE

General Electric introduces polycarbonate (Lexan), a transparent and impact-resistant thermoplastic used in eyewear, electronics, and automotive. #polymer #materials

Polycarbonate Introduced by GE
Polycarbonate Introduced by GE
By Ed (Edgar181) - Own work, Public domain, https://commons.wikimedia.org/w/index.php?curid=52831270
1963 CE

Ziegler and Natta Win Nobel Prize

Karl Ziegler and Giulio Natta receive the Nobel Prize in Chemistry for their discoveries in the field of high polymers and catalysis. #polymer #science

1965 CE

Stephanie Kwolek Invents Kevlar

Stephanie Kwolek at DuPont discovers Kevlar, a para-aramid synthetic fiber with exceptional strength-to-weight ratio, used in bulletproof vests and composites. #polymer #materials

Stephanie Kwolek Invents Kevlar
Stephanie Kwolek Invents Kevlar
By Ben Mills and Jynto - Derived from File:Benzene-aromatic-3D-balls.png and File:Oxamide-3D-balls.png., Public domain, https://commons.wikimedia.org/w/index.php?curid=9854604
1971 CE

Discovery of Conducting Polymers: Polyacetylene

Hideki Shirakawa, Alan MacDiarmid, and Alan Heeger synthesize polyacetylene and demonstrate high electrical conductivity when doped, founding conducting polymer research. #polymer #science

Discovery of Conducting Polymers: Polyacetylene
Discovery of Conducting Polymers: Polyacetylene
By Smokefoot - Own work, Public domain, https://commons.wikimedia.org/w/index.php?curid=6893639
1974 CE

Polyethylene Terephthalate (PET) Bottles Introduced

PET is first used for carbonated beverage bottles, revolutionizing packaging due to its clarity, strength, and recyclability. #polymer #packaging

Polyethylene Terephthalate (PET) Bottles Introduced
Polyethylene Terephthalate (PET) Bottles Introduced
By Schippmeister - Own work, CC BY-SA 4.0, https://commons.wikimedia.org/w/index.php?curid=82979191
1977 CE

Conducting Polymers Breakthrough

Shirakawa, MacDiarmid, and Heeger publish their results on iodine-doped polyacetylene, achieving metallic conductivity and paving the way for organic electronics. #polymer #science

1980 CE

Polymerase Chain Reaction (PCR) Invented

Kary Mullis invents PCR, a method using DNA polymerase to amplify DNA sequences, transforming molecular biology and diagnostics. #polymer #biotech

Polymerase Chain Reaction (PCR) Invented
Polymerase Chain Reaction (PCR) Invented
By Madprime - Own work, CC0, https://commons.wikimedia.org/w/index.php?curid=2104468
1983 CE

First Water-Soluble Polymer for Drug Delivery

Development of poly(ethylene glycol) (PEG) conjugation (PEGylation) to improve drug solubility and half-life, first approved for clinical use. #polymer #biomedical

First Water-Soluble Polymer for Drug Delivery
First Water-Soluble Polymer for Drug Delivery
By Ed (Edgar181) - Own work, Public domain, https://commons.wikimedia.org/w/index.php?curid=52936339
1985 CE

Discovery of Fullerenes

Harold Kroto, James Heath, Sean O'Brien, Robert Curl, and Richard Smalley discover fullerenes (C60), carbon allotropes with polymer-like structures, leading to new materials. #polymer #chemistry

Discovery of Fullerenes
Discovery of Fullerenes
By 痛 - Own work, CC BY-SA 4.0, https://commons.wikimedia.org/w/index.php?curid=118428240
1990 CE

First Conjugated Polymer Light-Emitting Diode (LED)

Richard Friend and colleagues at Cambridge demonstrate the first polymer LED using poly(p-phenylene vinylene) (PPV), launching plastic electronics. #polymer #electronics

First Conjugated Polymer Light-Emitting Diode (LED)
First Conjugated Polymer Light-Emitting Diode (LED)
By STRONGlk7 - Own work, CC BY-SA 3.0, https://commons.wikimedia.org/w/index.php?curid=22585310
1991 CE

Discovery of Carbon Nanotubes

Sumio Iijima discovers multi-walled carbon nanotubes, which have exceptional mechanical and electrical properties, promising for polymer composites. #polymer #nanotech

Discovery of Carbon Nanotubes
Discovery of Carbon Nanotubes
By Original hochgeladen von Schwarzm am 30. Aug 2004; Selbst gemacht mit C4D/Cartoonrenderer, GNU FDL - German Wikipedia, original upload 29. Dez 2004 by APPER, CC BY-SA 3.0, https://commons.wikimedia.org/w/index.php?curid=350208
2000 CE

Nobel Prize for Conducting Polymers

Shirakawa, MacDiarmid, and Heeger receive the Nobel Prize in Chemistry for the discovery and development of conductive polymers. #polymer #science

2002 CE

Controlled Radical Polymerization Methods Mature

ATRP (atom transfer radical polymerization) and RAFT (reversible addition-fragmentation chain transfer) become widely adopted for precise polymer synthesis. #polymer #chemistry

Controlled Radical Polymerization Methods Mature
Controlled Radical Polymerization Methods Mature
By Ben Mills and Jynto - Derivative of File:Trans-butadiene-3D-balls.png., Public domain, https://commons.wikimedia.org/w/index.php?curid=9371622
2004 CE

Graphene Isolated

Andre Geim and Konstantin Novoselov isolate graphene, a single-layer carbon material, opening up new opportunities for polymer nanocomposites. #polymer #materials

Graphene Isolated
Graphene Isolated
By AlexanderAlUS - Own work, CC BY-SA 3.0, https://commons.wikimedia.org/w/index.php?curid=11294534
2005 CE

Self-Healing Polymers Developed

Researchers at the University of Illinois develop self-healing polymer materials that can repair cracks autonomously using embedded microcapsules. #polymer #materials

Self-Healing Polymers Developed
Self-Healing Polymers Developed
By Jejmule - Own work, CC BY-SA 4.0, https://commons.wikimedia.org/w/index.php?curid=55714245
2007 CE

First 3D Printing of Polymers

RepRap project introduces open-source 3D printing using polylactic acid (PLA) filaments, democratizing additive manufacturing. #polymer #technology

First 3D Printing of Polymers
First 3D Printing of Polymers
By RepRapPro - YouTube: https://www.youtube.com/watch?v=r5nDrae3gJg – View/save archived versions on archive.org, CC BY 3.0, https://commons.wikimedia.org/w/index.php?curid=45334835
2010 CE

Polymer-Based Organic Photovoltaics Reach 10% Efficiency

Organic solar cells using conjugated polymers achieve 10% power conversion efficiency, spurring research into flexible solar panels. #polymer #energy

Polymer-Based Organic Photovoltaics Reach 10% Efficiency
Polymer-Based Organic Photovoltaics Reach 10% Efficiency
By Solarmer (talk) - Own work (Original text: I created this work entirely by myself.), Public domain, https://commons.wikimedia.org/w/index.php?curid=6730117
2015 CE

Polymer Nanocomposites for Medical Implants

Development of biodegradable polymer nanocomposites for bone scaffolds and implants, integrating polymers with bioactive ceramics. #polymer #biomedical

Polymer Nanocomposites for Medical Implants
Polymer Nanocomposites for Medical Implants
By Unknown author, CC BY-SA 3.0, https://commons.wikimedia.org/w/index.php?curid=26030
2018 CE

Chemical Recycling of Polymers Advances

New catalytic methods for depolymerizing plastics like PET and polyolefins into monomers enable circular economy for polymers. #polymer #environment

2020 CE

Biobased Polyethylene from Sugar Cane

Braskem and other companies scale up production of biobased polyethylene from ethanol derived from sugarcane, reducing carbon footprint. #polymer #sustainability

Biobased Polyethylene from Sugar Cane
Biobased Polyethylene from Sugar Cane
By Scott Bauer - This image was released by the Agricultural Research Service, the research agency of the United States Department of Agriculture, with the ID k7245-1 (next)., Public domain, https://commons.wikimedia.org/w/index.php?curid=1675054
2022 CE

Machine Learning for Polymer Design

Artificial intelligence and machine learning models are applied to predict polymer properties and accelerate discovery of new materials. #polymer #AI